That's a little harder than it sounds: the secondary factory DPs twist in a very special way to accommodate the cats without affecting ground clearance. When you move to 2.5", accomplishing that requires very similar twisting or moving the cats closer to the primary DP connection point in which clearance overall still might be an issue. It might not be worth the hassle compared to the simplicity of a pair of cats on the primaries.
Having said that, I believe someone here has put 200 cell cats on the secondary DPs on a 2.5" diameter pipe, but I would just stick to a single 400 cell on the primary if I had the option. There's not a lot of room to work with cats on the secondary DP which is why you don't see any offerings of secondary DPs with cats

I'd know because my secondaries are custom made, so I was down there, lol